Holy Roman Empire and Chibitalia In my opinion it's the cutest pairing in Hetalia. And I am going to throw a brick at Hidekaz face if it turns out HRE and Germany are different people. I have so many pairings outside of Hetalia, but I still find this adorable!
********SPOILERS****************My favourite couple is Shigure and Akito from Fruits Basket. They are both very complex and well-developed characters (possibly più so in the manga, although I haven't watched all the Anime yet), and because of this I think they make a più interesting couple than some other Anime couples. Many people seem to hate Akito-I actually quite like her, even if she did stab Kureno, one of my favourite characters-yet Shigure seems to remain reasonably popular, which is interesting as, though Shigure is one of my fave characters, he has a much darker side in the manga. I wonder if he would be quite as popolare if the Anime hadn't been made.
Syaoran and Sakura from Tsubasa : Reservoir Chronicles and Card Captor Sakura .
In both anime's Syaoran is willing to do anything in order to protect Sakura even if she might not feel the same way and is even shown to be willing to risk his own life o happiness' as long as Sakura is okay . Sakura on the other hand cares for Syaoran but not in the same way at first , but in the end it's actually very cuore warming when she finally confesses her feelings to Syoaran .