Kisuke Urahara as captain of the 12th division
Kisuke is the owner of the Urahara Shop, which sells various Shinigami items.After Ichigo Kurosaki becomes a Shinigami, he becomes his informal teacher, helping and tutoring him in the ways of the Shinigami, and preparing him to face off with tough opponents. Later it is revealed that he was a captain in Soul Society and an inventor, having developed numerous devices used da the Shinigami. He was exiled for a crime which he had not committed, and has taken up residence in the human world since that point. Nevertheless, he remains to be a valuable ally to Soul Society in their ongoing war with...
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