Well, let's see...
I think Fullmetal Alchemist is a good show. It has some mildly disturbing bits and some blood and gore, though, in case te wanted to watch something with a younger sibling o something.
I really like Loveless. I don't know if te have already watched it, but it's an excellent anime. It's a little confusing at first, but if te keep watching, you'll understand what's going on. It's yaoi, though, in case te don't like that.
Ghost Hound is good, too, in my opinion. It's another one that's confusing at first. It has a lot of psychology mixed in, and Supernatural elements.
I watched about one fourth of Angel Feather. It seems pretty good, but I'm not positive yet. Another yaoi.
You've probably already watched Ouran High School Host Club (most people I've talked to about Anime have) but if not, it's very funny. I don't usually like shows like it (high school shows, were school is the setting and a lot of the plot) but it's definitely an exception.
Sorry if I was too descriptive. Here's a link to a lista of Anime if te still need a few. :) The site is WOT safe, da the why.
link