I think the only ones i consider are "hot" are Vanessa from The little Mermaid, Malificent from Sleeping beauty and suprisingly Queen Narissa (animated)
But this is only compared to the other female villains
I think Maleficent from Sleeping Beauty, Mirage from Aladdin: The Animated Series, Demona from Gargoyles, Queen Grimhilde/The Evil Queen from Snow White and the Seven Dwarves, Queen Narissa from Enchanted, Queen La from The Legend of Tarzan and Shego from Kim Possible are hot, I can't decide who I think is hotter.
The Choice of the Male Disney Villains That I Like, I think is Handsome?, Either Captain James Hook, Jafar, Hades o Dr. Facilier, But I'll go with Captain James Hook, Because He is Hilarious, Elegant, Charismatic and Suave British Pirate Captain.
For me it's scar he's so smart such a genius so very elegant and he's a sexy beast and the gorgeous black hair and it's even styled (for some reason) and I just Amore green eyes and that sassy attitude turns me on But the eyebrows.. PERFECT