I don't know if you've seen the episode but... maybe spoiler if te haven't seen it but... yes. His name was Adam. They shared the same father. But it turned out a ghoul went after Adam and his mother and the brother's found that out later. Adam was already deceased. The brother and mother te see in the episodes are ghouls.
Yes adam was really their brother, half-brother at least, their dad slept with adams mum on a hunt. But some ghouls wanted revenge on John and killed Adam and his mum. So although Adam was really Sam and Deans brother the Adam te see in the episode is a ghoul.
